According to documentation no is possible.
To specify a single literal quote, escape it with a slash
inverted (). To specify a backslash, double-click (\).
All other backslash instances will be treated as one
literal backslash: this means that the other
exhaust that you can use to, such as \ r or \ n, will be issued
literally, as specified instead of having any meaning
special.
Note: Unlike the syntax for double quotation marks , and
a href="http://www.php.net/manual/en/language.variables.php"> variables and
escape sequences for special characters will not be replaced
when they occur inside quoted strings.
What you can do is to use concatenation yourself.
$video['chave'] = "valor";
echo '<span class="video">{' .$video['chave'] .'}</span>';