The friendly URL is important in these cases:
Better user viewing
Not only the URL in the browser tab as long as the user browses, but if he favors the page, share it with his colleagues through messages, they will know what it is about before even opening the page.
Search Engine Indexing
It is more likely that a search engine will find the page post using the URL as a reference. Example: when searching for stackoverflow, search engines quickly identify the URL in question, when searching for a question (which you know exists on this site), you will quickly find the title that is defined in both the URL and the tag and also how h1 (you can see on this page for example), is an additional and important reference.
Confidence
The experienced user reviews the link before clicking it. Note that you've even been insecure with shortened links like " link ". When you view a title or something of the genre, your confidence increases: link
Security
You can have more protection, because you will not be leaving your exposed files of type: 'www.examplecompany.com.br/produtos.php?id=32', that necessarily a search for better use of the user and for the distribution of information you will have to pass the parameters by "GET".