Error when deploying a java application with postgres

Expensive.

I created a small web application using postgres. However, when I run the eclipse, it runs smoothly. But when I export the .war file and try to deploy it on the tomcat server, it returns the error below:

Caused by: javax.persistence.PersistenceException: Unable to build entity manager factory
    at org.hibernate.jpa.HibernatePersistenceProvider.createEntityManagerFactory(HibernatePersistenceProvider.java:83)
    at org.hibernate.ejb.HibernatePersistence.createEntityManagerFactory(HibernatePersistence.java:54)
    at javax.persistence.Persistence.createEntityManagerFactory(Persistence.java:55)
    at org.springframework.orm.jpa.LocalEntityManagerFactoryBean.createNativeEntityManagerFactory(LocalEntityManagerFactoryBean.java:96)
    at org.springframework.orm.jpa.AbstractEntityManagerFactoryBean.afterPropertiesSet(AbstractEntityManagerFactoryBean.java:318)
    at org.springframework.beans.factory.support.AbstractAutowireCapableBeanFactory.invokeInitMethods(AbstractAutowireCapableBeanFactory.java:1633)
    at org.springframework.beans.factory.support.AbstractAutowireCapableBeanFactory.initializeBean(AbstractAutowireCapableBeanFactory.java:1570)
    ... 45 more
Caused by: org.hibernate.exception.JDBCConnectionException: Error calling Driver#connect
    at org.hibernate.exception.internal.SQLStateConversionDelegate.convert(SQLStateConversionDelegate.java:132)
    at org.hibernate.engine.jdbc.connections.internal.BasicConnectionCreator$1$1.convert(BasicConnectionCreator.java:118)
    at org.hibernate.engine.jdbc.connections.internal.BasicConnectionCreator.convertSqlException(BasicConnectionCreator.java:140)
    at org.hibernate.engine.jdbc.connections.internal.DriverConnectionCreator.makeConnection(DriverConnectionCreator.java:58)
    at org.hibernate.engine.jdbc.connections.internal.BasicConnectionCreator.createConnection(BasicConnectionCreator.java:75)
    at org.hibernate.engine.jdbc.connections.internal.DriverManagerConnectionProviderImpl.configure(DriverManagerConnectionProviderImpl.java:106)
    at org.hibernate.boot.registry.internal.StandardServiceRegistryImpl.configureService(StandardServiceRegistryImpl.java:111)
    at org.hibernate.service.internal.AbstractServiceRegistryImpl.initializeService(AbstractServiceRegistryImpl.java:234)
    at org.hibernate.service.internal.AbstractServiceRegistryImpl.getService(AbstractServiceRegistryImpl.java:206)
    at org.hibernate.engine.jdbc.internal.JdbcServicesImpl.buildJdbcConnectionAccess(JdbcServicesImpl.java:260)
    at org.hibernate.engine.jdbc.internal.JdbcServicesImpl.configure(JdbcServicesImpl.java:94)
    at org.hibernate.boot.registry.internal.StandardServiceRegistryImpl.configureService(StandardServiceRegistryImpl.java:111)
    at org.hibernate.service.internal.AbstractServiceRegistryImpl.initializeService(AbstractServiceRegistryImpl.java:234)
    at org.hibernate.service.internal.AbstractServiceRegistryImpl.getService(AbstractServiceRegistryImpl.java:206)
    at org.hibernate.cfg.Configuration.buildTypeRegistrations(Configuration.java:1887)
    at org.hibernate.cfg.Configuration.buildSessionFactory(Configuration.java:1845)
    at org.hibernate.jpa.boot.internal.EntityManagerFactoryBuilderImpl$4.perform(EntityManagerFactoryBuilderImpl.java:857)
    at org.hibernate.jpa.boot.internal.EntityManagerFactoryBuilderImpl$4.perform(EntityManagerFactoryBuilderImpl.java:850)
    at org.hibernate.boot.registry.classloading.internal.ClassLoaderServiceImpl.withTccl(ClassLoaderServiceImpl.java:425)
    at org.hibernate.jpa.boot.internal.EntityManagerFactoryBuilderImpl.build(EntityManagerFactoryBuilderImpl.java:849)
    at org.hibernate.jpa.HibernatePersistenceProvider.createEntityManagerFactory(HibernatePersistenceProvider.java:75)
    ... 51 more
Caused by: org.postgresql.util.PSQLException: The connection attempt failed.
    at org.postgresql.core.v3.ConnectionFactoryImpl.openConnectionImpl(ConnectionFactoryImpl.java:292)
    at org.postgresql.core.ConnectionFactory.openConnection(ConnectionFactory.java:49)
    at org.postgresql.jdbc.PgConnection.<init>(PgConnection.java:195)
    at org.postgresql.Driver.makeConnection(Driver.java:454)
    at org.postgresql.Driver.connect(Driver.java:256)
    at org.hibernate.engine.jdbc.connections.internal.DriverConnectionCreator.makeConnection(DriverConnectionCreator.java:55)
    ... 68 more
Caused by: java.net.SocketTimeoutException: connect timed out
    at java.net.PlainSocketImpl.socketConnect(Native Method)
    at java.net.AbstractPlainSocketImpl.doConnect(AbstractPlainSocketImpl.java:350)
    at java.net.AbstractPlainSocketImpl.connectToAddress(AbstractPlainSocketImpl.java:206)
    at java.net.AbstractPlainSocketImpl.connect(AbstractPlainSocketImpl.java:188)
    at java.net.SocksSocketImpl.connect(SocksSocketImpl.java:392)
    at java.net.Socket.connect(Socket.java:589)
    at org.postgresql.core.PGStream.<init>(PGStream.java:70)
    at org.postgresql.core.v3.ConnectionFactoryImpl.tryConnect(ConnectionFactoryImpl.java:91)
    at org.postgresql.core.v3.ConnectionFactoryImpl.openConnectionImpl(ConnectionFactoryImpl.java:192)
    ... 73 more

The database is connected. I went to tomcat's conf / server.xml file to change the timout and it looks like this

Note: I execute in eclipse successfully and immediately export the .war and when I try to deploy it returns the error. Any other way I can set the timout?