The message tells you to use the "file" command to load the file.
(gdb) exec-file test
(gdb) b 2
No symbol table is loaded. Use the "file" command.
(gdb) file test
Reading symbols from /home/user/test/test...done.
(gdb) b 2
Breakpoint 1 at 0x80483ea: file test.c, line 2.
(gdb)
You can also try to pass the program on the command line
$ gdb test
GNU gdb (GDB) 7.4
Copyright (C) 2012 Free Software Foundation, Inc.
License GPLv3+: GNU GPL version 3 or later <http://gnu.org/licenses/gpl.html>
[...]
Reading symbols from /home/user/test/test...done.
(gdb) b 2
Breakpoint 1 at 0x80483ea: file test.c, line 2.
(gdb)