You can not use 2 elses without conditions in a row.
Or you put a condition (else if ()), or close the if "parent" with a "}" before the second else:
if(is_numeric($id) && $id >=1){
$stmt = $obj_mysqli->prepare("UPDATE 'clientes' SET 'nome'=$nome, 'email'=$email, 'cidade'=$cidade, 'uf'=$uf WHERE id= $id");
$stmt->bind_param('ssssi', $nome, $email, $cidade, $uf, $id);
if(!$stmt->execute()){
$erro = $stmt->error;
}
else{
header("Location:cadastro.php");
exit;
}
}
else {
$erro = "Número Inválido";
}