Add e-mail with copy in form submission

I have developed an email form but I need to add another email to receive a copy. I have no idea how to do this. Follow my code

PHP:

<?php
if($_POST)
{
    $to_Email       = "[email protected]"; //Replace with recipient email address
    $subject        = 'Contato para contratação de serviços'; //Subject line for emails


    //check if its an ajax request, exit if not
    if(!isset($_SERVER['HTTP_X_REQUESTED_WITH']) AND strtolower($_SERVER['HTTP_X_REQUESTED_WITH']) != 'xmlhttprequest') {

        //exit script outputting json data
        $output = json_encode(
        array(
            'type'=>'error',
            'text' => 'Request must come from Ajax'
        ));

        die($output);
    }

    //check $_POST vars are set, exit if any missing
    if(!isset($_POST["userName"]) || !isset($_POST["userEmail"]) || !isset($_POST["userMessage"]))
    {
        $output = json_encode(array('type'=>'error', 'text' => 'Os campos de entrada estão vazios!  '));
        die($output);
    }

    //Sanitize input data using PHP filter_var().
    $user_Name        = filter_var($_POST["userName"], FILTER_SANITIZE_STRING);
    $user_Email       = filter_var($_POST["userEmail"], FILTER_SANITIZE_EMAIL);
    $user_Phone =                  $_POST["userTelephone"];
    $user_Service       = filter_var($_POST["userService"], FILTER_SANITIZE_EMAIL);
    $user_Message     = filter_var($_POST["userMessage"], FILTER_SANITIZE_STRING);

    //additional php validation
    if(strlen($user_Name)<3) // If length is less than 3 it will throw an HTTP error.
    {
        $output = json_encode(array('type'=>'error', 'text' => 'O campo nome não pode ficar vazio'));
        die($output);
    }
    if(!filter_var($user_Email, FILTER_VALIDATE_EMAIL)) //email validation
    {
        $output = json_encode(array('type'=>'error', 'text' => 'Por favor ultilize um e-mail válido'));
        die($output);
    }

    if(strlen($user_Message)<5) //check emtpy message
    {
        $output = json_encode(array('type'=>'error', 'text' => 'Por favor insira uma mensagem'));
        die($output);
    }


    $message_Body = "<strong>Name: </strong>". $user_Name ."<br>";
    $message_Body .= "<strong>Email: </strong>". $user_Email ."<br>";
    $message_Body .= "<strong>Phone: </strong>". $user_Phone ."<br>";
    $message_Body .= "<strong>Serviço: </strong>". $user_Service ."<br>";
    $message_Body .= "<strong>Message: </strong>". $user_Message ."<br>";



    $headers = "From: " . strip_tags($user_Email) . "\r\n";
    $headers .= "Reply-To: ". strip_tags($user_Email) . "\r\n";
    $headers .= "MIME-Version: 1.0\r\n";
    $headers .= "Content-Type: text/html; charset=UTF-8\r\n";



    //proceed with PHP email.
    $headers = 'From: '.$user_Email.'' . "\r\n" .
    'Reply-To: '.$user_Email.'' . "\r\n" .
    'X-Mailer: PHP/' . phpversion(). "\r\n" .
    'Content-type: text/html;charset=UTF-8';



    $sentMail = @mail($to_Email, $subject, $message_Body, $headers);

    if(!$sentMail)
    {
        $output = json_encode(array('type'=>'error', 'text' => 'Ocorreu um erro tente novamente'));
        die($output);
    }else{
        $output = json_encode(array('type'=>'message', 'text' => 'Olá '. $user_Name .' Obrigado pelo seu contato retornaremos em breve.'));
        die($output);
    }
}
?>

and JS:

//Contact Us
$("#submit_btn").click(function() {
    //get input field values
    var user_name       = $('input[name=name]').val();
    var user_email      = $('input[name=email]').val();
    var user_telephone      = $('input[name=phone]').val();
    var user_service      = $('input[name=service]').val();
    var user_message    = $('textarea[name=message]').val();

    //simple validation at client's end
    var post_data, output;
    var proceed = true;
    if(user_name==""){
        proceed = false;
    }
    if(user_email==""){
        proceed = false;
    }
    if(user_message=="") {
        proceed = false;
    }

    //everything looks good! proceed...
    if(proceed)
    {
        //data to be sent to server
        post_data = {'userName':user_name, 'userEmail':user_email, 'userTelephone':user_telephone, 'userService':user_service, 'userMessage':user_message};

        //Ajax post data to server
        $.post('contact.php', post_data, function(response){

            //load json data from server and output message
            if(response.type == 'error')
            {
                output = '<div class="alert-danger" style="padding:10px; margin-bottom:25px;">'+response.text+'</div>';
            }else{
                output = '<div class="alert-success" style="padding:10px; margin-bottom:25px;">'+response.text+'</div>';

                //reset values in all input fields
                $('#form-elements input').val('');
                $('#form-elements textarea').val('');
            }

            $("#result").hide().html(output).slideDown();
        }, 'json');

    }
});

//reset previously set border colors and hide all message on .keyup()
$("#form-elements input, #form-elements textarea").keyup(function() {
    $("#result").slideUp();
});

NOTE: I do not think HTML is needed here