You can use CharIndex () and < SubString () to do what you need.
First we must find the delimiter character, in its case the comma.
After this we will look for what comes before and after the comma, like this:
select
Substring(nome, Charindex(',', nome)+1, LEN(nome)) as Nome,
Substring(nome, 1,Charindex(',', nome)-1) as LastName,
from Pessoas
Now, for what you need, just concatenate the two, thus:
select
Substring(nome, Charindex(',', nome)+1, LEN(nome)) + ' ' + Substring(nome, 1,Charindex(',', nome)-1) as Nome
from pessoas
In this Link has a small tutorial of functions.